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Inducing Curvature to Pyracylene upon π‐Expansion

We disclose a successive π‐expansion of pyracylene towards boat‐shaped polycyclic scaffolds. The unique structural features of the resulting compounds were revealed by X‐ray crystallographic analysis. Depending on the extent of π‐expansion the compounds display intense bathochromically shifted absor...

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Detalles Bibliográficos
Autores principales: Bergner, John, Walla, Christian, Rominger, Frank, Dreuw, Andreas, Kivala, Milan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9543126/
https://www.ncbi.nlm.nih.gov/pubmed/35652474
http://dx.doi.org/10.1002/chem.202201554