Cargando…

Inducing Curvature to Pyracylene upon π‐Expansion

We disclose a successive π‐expansion of pyracylene towards boat‐shaped polycyclic scaffolds. The unique structural features of the resulting compounds were revealed by X‐ray crystallographic analysis. Depending on the extent of π‐expansion the compounds display intense bathochromically shifted absor...

Descripción completa

Detalles Bibliográficos
Autores principales:	Bergner, John, Walla, Christian, Rominger, Frank, Dreuw, Andreas, Kivala, Milan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9543126/ https://www.ncbi.nlm.nih.gov/pubmed/35652474 http://dx.doi.org/10.1002/chem.202201554

Ejemplares similares

A Symmetrically π‐Expanded Carbazole Incorporating Fluoranthene Moieties
por: Vogel, Alexander, et al.
Publicado: (2022)

Fully Bridged Triphenylamines Comprising Five‐ and Seven‐Membered Rings
por: Michalsky, Ina, et al.
Publicado: (2022)

Reduction of π‐Expanded Cyclooctatetraene with Lithium: Stabilization of the Tetra‐Anion through Internal Li(+) Coordination
por: Zhou, Zheng, et al.
Publicado: (2020)

Oxidative Cyclodehydrogenation of Trinaphthylamine: Selective Formation of a Nitrogen‐Centered Polycyclic π‐System Comprising 5‐ and 7‐Membered Rings
por: Nebauer, Johannes, et al.
Publicado: (2022)

Tetra(peri‐naphthylene)anthracene: A Near‐IR Fluorophore with Four‐Stage Amphoteric Redox Properties
por: Frisch, Sabine, et al.
Publicado: (2022)

Thiophenylazobenzene: An Alternative Photoisomerization Controlled by Lone‐Pair⋅⋅⋅π Interaction
por: Slavov, Chavdar, et al.
Publicado: (2019)

On-surface synthesis of π-conjugated ladder-type polymers comprising nonbenzenoid moieties
por: Urgel, José I., et al.
Publicado: (2021)

[6π] Photocyclization to cis-Hexahydrocarbazol-4-ones: Substrate Modification, Mechanism, and Scope
por: Modha, Sachin G., et al.
Publicado: (2019)

Phosphorus‐Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry
por: Ascherl, Johannes D. R., et al.
Publicado: (2020)

Two Cases of Angular Curvature, Supervening upon Lateral Curvature of the Spine
por: Earle, F. O.
Publicado: (1866)

Pre‐Planarized Triphenylamine‐Based Linear Mixed‐Valence Charge‐Transfer Systems
por: Krug, Marcel, et al.
Publicado: (2021)

Gradient expansion, curvature perturbations and magnetized plasmas
por: Giovannini, Massimo, et al.
Publicado: (2011)

XABOOM: An X-ray Absorption Benchmark of Organic Molecules Based on Carbon, Nitrogen, and Oxygen 1s → π* Transitions
por: Fransson, Thomas, et al.
Publicado: (2021)

A Stable Hexaazaoctacene Cruciform σ‐Dimer
por: Maier, Steffen, et al.
Publicado: (2022)

Study of the Y-π, K-π AND π-π interactions
por: Franzini, P., et al.
Publicado: (1961)

Modular Two‐Step Access to π‐Extended Naphthyridine Systems—Potent Building Blocks for Organic Electronics
por: Stuck, Fabian, et al.
Publicado: (2021)

5,7,12,14‐Tetrafunctionalized 6,13‐Diazapentacenes
por: Xie, Gaozhan, et al.
Publicado: (2019)

Persistent Ambipolar Heptacenes and Their Redox Species
por: Zeitter, Nico, et al.
Publicado: (2022)

Stable Radical Cations of N,N′‐Diarylated Dihydrodiazapentacenes
por: Xie, Gaozhan, et al.
Publicado: (2019)

A Doubly Bridged Bis(phenylethynyl)benzene: Different from a Twisted Tolan
por: Hodecker, Manuel, et al.
Publicado: (2020)

Resonances in pp¯ → ηπ+π−π+π− at rest
por: Anisovich, A V, et al.
Publicado: (2001)

Differences in thermal expansion and motion ability for herringbone and face-to-face π-stacked solids
por: Ding, Xiaodan, et al.
Publicado: (2021)

Coupled channel analysis of proton-antiproton annihilation into π0π0π0, π0ηη and π0π0η
por: Amsler, C, et al.
Publicado: (1995)

Stress Buildup Upon Crystallization of GeTe Thin Films: Curvature Measurements and Modelling
por: Tholapi, Rajkiran, et al.
Publicado: (2020)

Adsorption of Antibiotics on Graphene and Biochar in Aqueous Solutions Induced by π-π Interactions
por: Peng, Bingquan, et al.
Publicado: (2016)

Proton-antiproton annihilation into π0π0π0, π0π0η and π0ηη at 900 MeV/c
por: Amsler, C
Publicado: (2001)

LHCb - Charm mixing in D0 → K±π∓π±π∓
por: Smallwood, Jennifer Clare
Publicado: (2022)

Isomeric Dithienophosphepines: The Impact of Ring Fusion on Electronic and Structural Properties
por: Padberg, Kevin, et al.
Publicado: (2020)

Noncovalent CH–π and π–π Interactions in Phosphoramidite Palladium(II) Complexes with Strong Conformational Preference
por: Žabka, Matej, et al.
Publicado: (2021)

Structure–property relationships and third-order nonlinearities in diketopyrrolopyrrole based D–π–A–π–D molecules
por: Podlesný, Jan, et al.
Publicado: (2017)

Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds
por: Chen, Xin, et al.
Publicado: (2020)

Ruthenium Complexes with Protic Ligands: Influence of the Position of OH Groups and π Expansion on Luminescence and Photocytotoxicity
por: Oladipupo, Olaitan E., et al.
Publicado: (2023)

On the Nature of σ–σ, σ–π, and π–π Stacking in Extended Systems
por: Cabaleiro-Lago, Enrique M., et al.
Publicado: (2018)

Blindness to Curvature and Blindness to Illusory Curvature
por: Bertamini, Marco, et al.
Publicado: (2018)

Synergy of Electrostatic and π–π Interactions in the Realization of Nanoscale Artificial Photosynthetic Model Systems
por: Anaya‐Plaza, Eduardo, et al.
Publicado: (2020)

Structural insights into the π-π-π stacking mechanism and DNA-binding activity of the YEATS domain
por: Klein, Brianna J., et al.
Publicado: (2018)

Supercurrent switch in π topological junctions based upon a narrow quantum spin Hall insulator
por: Yu, Qingyun, et al.
Publicado: (2017)

Force-induced retro-click reaction of triazoles competes with adjacent single-bond rupture
por: Stauch, Tim, et al.
Publicado: (2017)

Thermodynamics of π–π Interactions of Benzene and Phenol in Water
por: Paik, Dooam, et al.
Publicado: (2022)

The tarani mutation alters surface curvature in Arabidopsis leaves by perturbing the patterns of surface expansion and cell division
por: Karidas, Premananda, et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_5f3efgbfkq8udersdjrtj4uuin