Reactions of Frustrated Lewis Pairs with Chloro‐Diazirines: Cleavage of N=N Double Bonds

The reactions of FLPs with diazomethanes leads to the rapid loss of N(2). In contrast, in this work, we reported reactions of phosphine/borane FLPs with chlorodiazirines which led to the reduction of the N=N double bond, affording linked phosphinimide/amidoborate zwitterions of the general form R(3)...

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Detalles Bibliográficos
Autores principales: Mandal, Dipendu, Chen, Ting, Qu, Zheng‐Wang, Grimme, Stefan, Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9543150/
https://www.ncbi.nlm.nih.gov/pubmed/35830598
http://dx.doi.org/10.1002/anie.202209241

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9543150/
https://www.ncbi.nlm.nih.gov/pubmed/35830598
http://dx.doi.org/10.1002/anie.202209241

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