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An Anionic Amido‐Substituted Seven‐Vertex Siliconoid Cluster
The silanide [Si(4){N(SiMe(3))Dipp}(3)](−) (1) transforms into the anionic siliconoid cluster [Si(7){N(SiMe(3))Dipp}(3)](−) (2) with four unsubstituted silicon atoms as a contact ion pair with [K([18]crown‐6)] in C(6)D(6) at room temperature within five weeks. Anion 2 was investigated by natural pop...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9543723/ https://www.ncbi.nlm.nih.gov/pubmed/35652723 http://dx.doi.org/10.1002/chem.202201473 |