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An Anionic Amido‐Substituted Seven‐Vertex Siliconoid Cluster
The silanide [Si(4){N(SiMe(3))Dipp}(3)](−) (1) transforms into the anionic siliconoid cluster [Si(7){N(SiMe(3))Dipp}(3)](−) (2) with four unsubstituted silicon atoms as a contact ion pair with [K([18]crown‐6)] in C(6)D(6) at room temperature within five weeks. Anion 2 was investigated by natural pop...
Autores principales: | Keuter, Jan, Dimitrova, Maria, Janka, Oliver, Hepp, Alexander, Berger, Raphael J. F., Lips, Felicitas |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9543723/ https://www.ncbi.nlm.nih.gov/pubmed/35652723 http://dx.doi.org/10.1002/chem.202201473 |
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