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[(CH(3))Al(CH(2))](12): Methylaluminomethylene (MAM‐12)

The molecular structure of enigmatic “poly(aluminium‐methyl‐methylene)” (first reported in 1968) has been unraveled in a transmetalation reaction with gallium methylene [Ga(8)(CH(2))(12)] and AlMe(3). The existence of cage‐like methylaluminomethylene moieties was initially suggested by the reaction...

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Detalles Bibliográficos
Autores principales: Spiridopoulos, Georgios, Kramer, Markus, Kracht, Felix, Maichle‐Mössmer, Cäcilia, Anwander, Reiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9544092/
https://www.ncbi.nlm.nih.gov/pubmed/35638696
http://dx.doi.org/10.1002/chem.202200823