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An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes

An adaptive catalytic system that provides control over the nitroarene hydrogenation network to prepare a wide range of aniline and hydroxylamine derivatives is presented. This system takes advantage of a delicate interplay between a rhodium(III) center and a Lewis acidic borane introduced in the se...

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Detalles Bibliográficos
Autores principales: Chugh, Vishal, Chatterjee, Basujit, Chang, Wei‐Chieh, Cramer, Hanna H., Hindemith, Carsten, Randel, Helena, Weyhermüller, Thomas, Farès, Christophe, Werlé, Christophe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9544374/
https://www.ncbi.nlm.nih.gov/pubmed/35759682
http://dx.doi.org/10.1002/anie.202205515