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An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes
An adaptive catalytic system that provides control over the nitroarene hydrogenation network to prepare a wide range of aniline and hydroxylamine derivatives is presented. This system takes advantage of a delicate interplay between a rhodium(III) center and a Lewis acidic borane introduced in the se...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9544374/ https://www.ncbi.nlm.nih.gov/pubmed/35759682 http://dx.doi.org/10.1002/anie.202205515 |