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Bistriazoles Connected Through a B−B Bridge, Synthesized by Highly Selective Dipolar Cycloaddition Reactions of a Diazido‐diborane(4)

In this work we report the first cycloaddition reactions between a diazido diborane(4) and terminal alkynes, providing unique access to bis‐1,2,3‐triazoles connected by a B−B bridge. The catalyst‐free reactions are highly selective, yielding exclusively the thermodynamically disfavored bis‐1,4‐triaz...

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Detalles Bibliográficos
Autores principales: Vogler, Daniel, Schöner, Maximilian, Kaifer, Elisabeth, Himmel, Hans‐Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9544427/
https://www.ncbi.nlm.nih.gov/pubmed/35703332
http://dx.doi.org/10.1002/chem.202201389