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Post‐Synthetic Modification of a Porous Hydrocarbon Cage to Give a Discrete Co(24) Organometallic Complex

A new alkyne‐based hydrocarbon cage was synthesized in high overall yield using alkyne‐alkyne coupling in the cage forming step. The cage is porous and displays a moderately high BET surface area (546 m(2) g(−1)). The cage loses crystallinity on activation and thus is porous in its amorphous form, w...

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Detalles Bibliográficos
Autores principales: Thomas, Chriso M., Liang, Weibin, Preston, Dan, Doonan, Christian J., White, Nicholas G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9544953/
https://www.ncbi.nlm.nih.gov/pubmed/35863888
http://dx.doi.org/10.1002/chem.202200958