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Post‐Synthetic Modification of a Porous Hydrocarbon Cage to Give a Discrete Co(24) Organometallic Complex
A new alkyne‐based hydrocarbon cage was synthesized in high overall yield using alkyne‐alkyne coupling in the cage forming step. The cage is porous and displays a moderately high BET surface area (546 m(2) g(−1)). The cage loses crystallinity on activation and thus is porous in its amorphous form, w...
Autores principales: | Thomas, Chriso M., Liang, Weibin, Preston, Dan, Doonan, Christian J., White, Nicholas G. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9544953/ https://www.ncbi.nlm.nih.gov/pubmed/35863888 http://dx.doi.org/10.1002/chem.202200958 |
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