Synthesis of New Morphinan Opioids by TBADT‐Catalyzed Photochemical Functionalization at the Carbon Skeleton

The synthesis of new morphinan opioids by the addition of photochemically generated carbon‐centered radicals to substrates containing an enone in the morphinan C‐ring, is described. Using tetrabutylammonium decatungstate (TBADT) as a hydrogen atom transfer photocatalyst, diverse radical donors can b...

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Detalles Bibliográficos
Autores principales: Gorbachev, Dmitry, Smith, Elliot, Argent, Stephen P., Newton, Graham N., Lam, Hon Wai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9544987/
https://www.ncbi.nlm.nih.gov/pubmed/35661287
http://dx.doi.org/10.1002/chem.202201478

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9544987/
https://www.ncbi.nlm.nih.gov/pubmed/35661287
http://dx.doi.org/10.1002/chem.202201478

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