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Lewis Base Catalyzed Synthesis of Sulfur Heterocycles via the C1‐Pyridinium Enolate

While the addition of C1‐Lewis base enolates to carbonyls and related structures are well established, the related addition to thiocarbonyls compounds are unknown. Herein, we report a reaction cascade in which a C1‐pyridinium enolate undergos addition to dithioesters, trithiocarbonates and xanthates...

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Detalles Bibliográficos
Autores principales: Cromwell, Simon, Sutio, Randy, Zhang, Changhe, Such, Georgina K., Lupton, David W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545057/
https://www.ncbi.nlm.nih.gov/pubmed/35718884
http://dx.doi.org/10.1002/anie.202206647