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Proton Conduction at High Temperature in High‐Symmetry Hydrogen‐Bonded Molecular Crystals of Ru(III) Complexes with Six Imidazole‐Imidazolate Ligands

A new H‐bonded crystal [Ru(III)(Him)(3)(Im)(3)] with three imidazole (Him) and three imidazolate (Im(−)) groups was prepared to obtain a higher‐temperature proton conductor than a Nafion membrane with water driving. The crystal is constructed by complementary N−H⋅⋅⋅N H‐bonds between the Ru(III) comp...

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Detalles Bibliográficos
Autores principales: Tadokoro, Makoto, Itoh, Masaki, Nishimura, Ryota, Sekiguchi, Kensuke, Hoshino, Norihisa, Kamebuchi, Hajime, Miyazaki, Jun, Kobayashi, Fumiya, Mizuno, Motohiro, Akutagawa, Tomoyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545294/
https://www.ncbi.nlm.nih.gov/pubmed/35760750
http://dx.doi.org/10.1002/chem.202201397