An Isolable 2,5‐Disila‐3,4‐Diphosphapyrrole and a Conjugated Si=P−Si=P−Si=N Chain Through Degradation of White Phosphorus with a N,N‐Bis(Silylenyl)Aniline

White phosphorus (P(4)) undergoes degradation to P(2) moieties if exposed to the new N,N‐bis(silylenyl)aniline PhNSi (2) 1 (Si=Si[N(tBu)](2)CPh), furnishing the first isolable 2,5‐disila‐3,4‐diphosphapyrrole 2 and the two novel functionalized Si=P doubly bonded compounds 3 and 4. The pathways for th...

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Detalles Bibliográficos
Autores principales: Xiong, Yun, Dong, Shicheng, Yao, Shenglai, Dai, Chenshu, Zhu, Jun, Kemper, Sebastian, Driess, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545316/
https://www.ncbi.nlm.nih.gov/pubmed/35876267
http://dx.doi.org/10.1002/anie.202209250

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545316/
https://www.ncbi.nlm.nih.gov/pubmed/35876267
http://dx.doi.org/10.1002/anie.202209250

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