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An Isolable 2,5‐Disila‐3,4‐Diphosphapyrrole and a Conjugated Si=P−Si=P−Si=N Chain Through Degradation of White Phosphorus with a N,N‐Bis(Silylenyl)Aniline
White phosphorus (P(4)) undergoes degradation to P(2) moieties if exposed to the new N,N‐bis(silylenyl)aniline PhNSi (2) 1 (Si=Si[N(tBu)](2)CPh), furnishing the first isolable 2,5‐disila‐3,4‐diphosphapyrrole 2 and the two novel functionalized Si=P doubly bonded compounds 3 and 4. The pathways for th...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545316/ https://www.ncbi.nlm.nih.gov/pubmed/35876267 http://dx.doi.org/10.1002/anie.202209250 |