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Two Novel Dinuclear Cobalt Polypyridyl Complexes in Electro‐ and Photocatalysis for Hydrogen Production: Cooperativity Increases Performance

Syntheses and mechanisms of two dinuclear Co‐polypyridyl catalysts for the H(2) evolution reaction (HER) were reported and compared to their mononuclear analogue (R1). In both catalysts, two di‐(2,2’‐bipyridin‐6‐yl)‐methanone units were linked by either 2,2’‐bipyridin‐6,6’‐yl or pyrazin‐2,5‐yl. Comp...

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Detalles Bibliográficos
Autores principales: Weder, Nicola, Grundmann, Nora S., Probst, Benjamin, Blacque, Olivier, Ketkaew, Rangsiman, Creazzo, Fabrizio, Luber, Sandra, Alberto, Roger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545343/
https://www.ncbi.nlm.nih.gov/pubmed/35765252
http://dx.doi.org/10.1002/cssc.202201049