Isolation of an Arsenic Diradicaloid with a Cyclic C(2)As(2)‐Core

Herein, we report on the synthesis, characterization, and reactivity studies of the first cyclic C(2)As(2)‐diradicaloid {(IPr)CAs}(2) (6) (IPr = C{N(Dipp)CH}(2); Dipp = 2,6‐iPr(2)C(6)H(3)). Treatment of (IPr)CH(2) (1) with AsCl(3) affords the Lewis adduct {(IPr)CH(2)}AsCl(3) (2). Compound 2 undergoe...

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Detalles Bibliográficos
Autores principales: Steffenfauseweh, Henric, Vishnevskiy, Yury V., Neumann, Beate, Stammler, Hans‐Georg, Andrada, Diego M., Ghadwal, Rajendra S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545666/
https://www.ncbi.nlm.nih.gov/pubmed/35652361
http://dx.doi.org/10.1002/anie.202207415

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545666/
https://www.ncbi.nlm.nih.gov/pubmed/35652361
http://dx.doi.org/10.1002/anie.202207415

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