The Heaviest Bottleable Metallylone: Synthesis of a Monatomic, Zero‐Valent Lead Complex (“Plumbylone”)

The elusive plumbylone {[Si(II)(Xant)Si(II)]Pb(0)} 3 stabilized by the bis(silylene)xanthene chelating ligand 1, [Si(II)(Xant)Si(II)=PhC(NtBu)(2)Si(Xant)Si(NtBu)(2)CPh], and its isolable carbonyl iron complex {[Si(II)(Xant)Si(II)]Pb(0)Fe(CO)(4)} 4 are reported. The compounds 3 and 4 were obtained st...

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Detalles Bibliográficos
Autores principales: Xu, Jian, Pan, Sudip, Yao, Shenglai, Frenking, Gernot, Driess, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545849/
https://www.ncbi.nlm.nih.gov/pubmed/35848899
http://dx.doi.org/10.1002/anie.202209442

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545849/
https://www.ncbi.nlm.nih.gov/pubmed/35848899
http://dx.doi.org/10.1002/anie.202209442

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