Hydrogen Tunneling in Catalytic Hydrolysis and Alcoholysis of Silanes

An unprecedented quantum tunneling effect has been observed in catalytic Si−H bond activations at room temperature. The cationic hydrido‐silyl‐iridium(III) complex, {Ir[SiMe(o‐C(6)H(4)SMe)(2)](H)(PPh(3))(THF)}[BAr(F) (4)], has proven to be a highly efficient catalyst for the hydrolysis and the alcoh...

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Detalles Bibliográficos
Autores principales: Almenara, Naroa, Garralda, Maria A., Lopez, Xabier, Matxain, Jon M., Freixa, Zoraida, Huertos, Miguel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545861/
https://www.ncbi.nlm.nih.gov/pubmed/35833924
http://dx.doi.org/10.1002/anie.202204558

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545861/
https://www.ncbi.nlm.nih.gov/pubmed/35833924
http://dx.doi.org/10.1002/anie.202204558

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