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Hydrogen Tunneling in Catalytic Hydrolysis and Alcoholysis of Silanes
An unprecedented quantum tunneling effect has been observed in catalytic Si−H bond activations at room temperature. The cationic hydrido‐silyl‐iridium(III) complex, {Ir[SiMe(o‐C(6)H(4)SMe)(2)](H)(PPh(3))(THF)}[BAr(F) (4)], has proven to be a highly efficient catalyst for the hydrolysis and the alcoh...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545861/ https://www.ncbi.nlm.nih.gov/pubmed/35833924 http://dx.doi.org/10.1002/anie.202204558 |