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Directed Dehydration as Synthetic Tool for Generation of a New Na(4)SnS(4) Polymorph: Crystal Structure, Na(+) Conductivity, and Influence of Sb‐Substitution

We present the convenient synthesis and characterization of the new ternary thiostannate Na(4)SnS(4) (space group [Formula: see text] ) by directed removal of crystal water molecules from Na(4)SnS(4)⋅14 H(2)O. The compound represents a new kinetically stable polymorph of Na(4)SnS(4), which is transf...

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Detalles Bibliográficos
Autores principales: Hartmann, Felix, Benkada, Assma, Indris, Sylvio, Poschmann, Michael, Lühmann, Henning, Duchstein, Patrick, Zahn, Dirk, Bensch, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9546091/
https://www.ncbi.nlm.nih.gov/pubmed/35648135
http://dx.doi.org/10.1002/anie.202202182