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Directed Dehydration as Synthetic Tool for Generation of a New Na(4)SnS(4) Polymorph: Crystal Structure, Na(+) Conductivity, and Influence of Sb‐Substitution
We present the convenient synthesis and characterization of the new ternary thiostannate Na(4)SnS(4) (space group [Formula: see text] ) by directed removal of crystal water molecules from Na(4)SnS(4)⋅14 H(2)O. The compound represents a new kinetically stable polymorph of Na(4)SnS(4), which is transf...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9546091/ https://www.ncbi.nlm.nih.gov/pubmed/35648135 http://dx.doi.org/10.1002/anie.202202182 |