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Topochemical, Single‐Crystal‐to‐Single‐Crystal [2+2] Photocycloadditions Driven by Chalcogen‐Bonding Interactions

The face‐to‐face association of (E)‐1,2‐di(4‐pyridyl)ethylene (bpen) molecules into rectangular motifs stabilized for the first time by chalcogen bonding (ChB) interactions is shown to provide photoreactive systems leading to cyclobutane formation through single‐crystal‐to‐single‐crystal [2+2] photo...

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Detalles Bibliográficos
Autores principales: Alfuth, Jan, Jeannin, Olivier, Fourmigué, Marc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9546344/
https://www.ncbi.nlm.nih.gov/pubmed/35797220
http://dx.doi.org/10.1002/anie.202206249