Covalent bond shortening and distortion induced by pressurization of thorium, uranium, and neptunium tetrakis aryloxides

Covalency involving the 5f orbitals is regularly invoked to explain the reactivity, structure and spectroscopic properties of the actinides, but the ionic versus covalent nature of metal-ligand bonding in actinide complexes remains controversial. The tetrakis 2,6-di-tert-butylphenoxide complexes of...

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Detalles Bibliográficos
Autores principales: Shephard, Jacob J., Berryman, Victoria E. J., Ochiai, Tatsumi, Walter, Olaf, Price, Amy N., Warren, Mark R., Arnold, Polly L., Kaltsoyannis, Nikolas, Parsons, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9546877/
https://www.ncbi.nlm.nih.gov/pubmed/36207297
http://dx.doi.org/10.1038/s41467-022-33459-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9546877/
https://www.ncbi.nlm.nih.gov/pubmed/36207297
http://dx.doi.org/10.1038/s41467-022-33459-7

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