Cargando…

Covalent bond shortening and distortion induced by pressurization of thorium, uranium, and neptunium tetrakis aryloxides

Covalency involving the 5f orbitals is regularly invoked to explain the reactivity, structure and spectroscopic properties of the actinides, but the ionic versus covalent nature of metal-ligand bonding in actinide complexes remains controversial. The tetrakis 2,6-di-tert-butylphenoxide complexes of...

Descripción completa

Detalles Bibliográficos
Autores principales:	Shephard, Jacob J., Berryman, Victoria E. J., Ochiai, Tatsumi, Walter, Olaf, Price, Amy N., Warren, Mark R., Arnold, Polly L., Kaltsoyannis, Nikolas, Parsons, Simon
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9546877/ https://www.ncbi.nlm.nih.gov/pubmed/36207297 http://dx.doi.org/10.1038/s41467-022-33459-7

Ejemplares similares

Contrasting behaviour under pressure reveals the reasons for pyramidalization in tris(amido)uranium(III) and tris(arylthiolate) uranium(III) molecules
por: Price, Amy N., et al.
Publicado: (2022)

Exceptional uranium(VI)-nitride triple bond covalency from (15)N nuclear magnetic resonance spectroscopy and quantum chemical analysis
por: Du, Jingzhen, et al.
Publicado: (2021)

Characterizing Pressure-Induced Uranium C=H Agostic Bonds**
por: Arnold, Polly L, et al.
Publicado: (2015)

Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes
por: Parmar, Vijay S., et al.
Publicado: (2021)

Metal–Metal Bonding in Uranium–Group 10 Complexes
por: Hlina, Johann A., et al.
Publicado: (2016)

Uranium and neptunium retention mechanisms in Gallionella ferruginea/ferrihydrite systems for remediation purposes
por: Krawczyk-Bärsch, Evelyn, et al.
Publicado: (2020)

Uranium and thorium complexes of the phosphaethynolate ion
por: Camp, Clément, et al.
Publicado: (2015)

Reduction chemistry of neptunium cyclopentadienide complexes: from structure to understanding
por: Dutkiewicz, Michał S., et al.
Publicado: (2017)

Correction to: Uranium and neptunium retention mechanisms in Gallionella ferruginea/ferrihydrite systems for remediation purposes
por: Krawczyk-Bärsch, Evelyn, et al.
Publicado: (2021)

Structural properties of ultra-small thorium and uranium dioxide nanoparticles embedded in a covalent organic framework
por: Moreau, Liane M., et al.
Publicado: (2020)

Thorium–ligand multiple bonds via reductive deprotection of a trityl group
por: Smiles, Danil E., et al.
Publicado: (2015)

DFT + U Study of Uranium Dioxide and Plutonium Dioxide with Occupation Matrix Control
por: Chen, Jia-Li, et al.
Publicado: (2022)

Uranium–nitride chemistry: uranium–uranium electronic communication mediated by nitride bridges
por: King, David M., et al.
Publicado: (2022)

Manual on radiological safety in uranium and thorium mines and mills
por: International Atomic Energy Agency. Vienna
Publicado: (1976)

Determination of Traces of Uranium and Thorium in Microelectronics Constituent Materials
por: Saisho, Hideo, et al.
Publicado: (1988)

Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)
por: Seed, John A., et al.
Publicado: (2022)

Production of neptunium and plutonium nuclides from uranium carbide using 1.4-GeV protons
por: Au, M., et al.
Publicado: (2023)

Carbene Complexes of Neptunium
por: Goodwin, Conrad A. P., et al.
Publicado: (2022)

Emergence of the structure-directing role of f-orbital overlap-driven covalency
por: Lu, Erli, et al.
Publicado: (2019)

Enhanced diffusion of Uranium and Thorium linked to crystal plasticity in zircon
por: Timms, Nicholas E, et al.
Publicado: (2006)

Interactions of proton and heavy ion beams with uranium and thorium targets
por: Barashenkov, V S, et al.
Publicado: (1996)

Fission of uranium, thorium and bismuth by 20 GeV protons
por: De Carvalho, H G, et al.
Publicado: (1962)

Monitoring and surveillance of residues from the mining and milling of uranium and thorium
por: International Atomic Energy Agency. Vienna
Publicado: (2002)

Synthesis, structure, and reactivity of uranium(vi) nitrides
por: Barluzzi, Luciano, et al.
Publicado: (2021)

Isolation of C1 through C4 derivatives from CO using heteroleptic uranium(iii) metallocene aryloxide complexes
por: Ward, Robert J., et al.
Publicado: (2023)

Safe management of wastes from the mining and milling of Uranium and Thorium ores
por: International Atomic Energy Agency. Vienna
Publicado: (1987)

Distribution of uranium and thorium chains radionuclides in different fractions of phosphogypsum grains
por: Szajerski, Piotr
Publicado: (2020)

A comparison of the chemo- and radiotoxicity of thorium and uranium at different enrichment grades
por: Rump, A., et al.
Publicado: (2023)

Correction: Isolation of C1 through C4 derivatives from CO using heteroleptic uranium(iii) metallocene aryloxide complexes
por: Ward, Robert J., et al.
Publicado: (2023)

Neptunium(III) copper(I) diselenide
por: Wells, Daniel M., et al.
Publicado: (2009)

The formation mechanism of uranium and thorium hydride phosphorus: a systematically theoretical study
por: Zhao, Huifeng, et al.
Publicado: (2019)

Determination of Trace Thorium and Uranium Impurities in Scandium with High Matrix by ICP-OES
por: She, Zhixuan, et al.
Publicado: (2023)

Redox interactions of technetium with neptunium in acid solutions
por: Chotkowski, Maciej
Publicado: (2018)

Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets
por: Parmar, Vijay S., et al.
Publicado: (2021)

Release and yields from thorium and uranium targets irradiated with a pulsed proton beam
por: Evensen, A H M, et al.
Publicado: (1997)

Evaluation of polybenzimidazole-based polymers for the removal of uranium, thorium and palladium from aqueous medium
por: Kumar, V. Vijaya, et al.
Publicado: (2018)

Thorium- and Uranium-Mediated C–H Activation of a Silyl-Substituted Cyclobutadienyl Ligand
por: Tsoureas, Nikolaos, et al.
Publicado: (2022)

Unprecedented pairs of uranium (iv/v) hydroxido and (iv/v/vi) oxido complexes supported by a seven-coordinate cyclen-anchored tris-aryloxide ligand
por: Löffler, Sascha T., et al.
Publicado: (2022)

Efficient and selective capture of thorium ions by a covalent organic framework
por: Liu, Xiaojuan, et al.
Publicado: (2023)

In-source laser resonance ionization spectroscopy of neptunium and plutonium
por: Au, Mia, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_sh2kashsrlh28fk2p0ccmb9r8h