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Charge-Separated Reactive Intermediates from the UV Photodissociation of Chlorobenzene in Solution

[Image: see text] Although ultraviolet (UV)-induced photochemical cleavage of carbon–halogen bonds in gaseous halocarbons is mostly homolytic, the photolysis of chlorobenzene in solution has been proposed to produce a phenyl cation, c-C(6)H(5)(+), which is a highly reactive intermediate of potential...

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Detalles Bibliográficos
Autores principales: Kao, Min-Hsien, Orr-Ewing, Andrew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9549464/
https://www.ncbi.nlm.nih.gov/pubmed/36148486
http://dx.doi.org/10.1021/acs.jpca.2c05327