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Excited-State Barrier Controls E → Z Photoisomerization in p-Hydroxycinnamate Biochromophores
[Image: see text] Molecules based on the deprotonated p-hydroxycinnamate moiety are widespread in nature, including serving as UV filters in the leaves of plants and as the biochromophore in photoactive yellow protein. The photophysical behavior of these chromophores is centered around a rapid E → Z...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9549896/ https://www.ncbi.nlm.nih.gov/pubmed/36149746 http://dx.doi.org/10.1021/acs.jpclett.2c02613 |