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Excited-State Barrier Controls E → Z Photoisomerization in p-Hydroxycinnamate Biochromophores

[Image: see text] Molecules based on the deprotonated p-hydroxycinnamate moiety are widespread in nature, including serving as UV filters in the leaves of plants and as the biochromophore in photoactive yellow protein. The photophysical behavior of these chromophores is centered around a rapid E → Z...

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Detalles Bibliográficos
Autores principales: Ashworth, Eleanor K., Coughlan, Neville J. A., Hopkins, W. Scott, Bieske, Evan J., Bull, James N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9549896/
https://www.ncbi.nlm.nih.gov/pubmed/36149746
http://dx.doi.org/10.1021/acs.jpclett.2c02613