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Electrophilic Trapping of Semibenzenes

[Image: see text] In this work, we demonstrate how allylative dearomatization of benzyl chlorides can provide direct access to a variety of semibenzenes. These scaffolds behave as highly reactive nucleophiles in the presence of carbocations. In addition, semibenzenes are susceptible to intramolecula...

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Detalles Bibliográficos
Autores principales: Boldrini, Cosimo, Reis, Marta Castiñeira, Harutyunyan, Syuzanna R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9552181/
https://www.ncbi.nlm.nih.gov/pubmed/36095222
http://dx.doi.org/10.1021/acs.joc.2c01331