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Photoinduced host-to-guest electron transfer in a self-assembled coordination cage

A [Pd(2)L(4)] coordination cage, assembled from electron-rich phenothiazine-based ligands and encapsulating an electron-deficient anthraquinone-based disulfonate guest, is reported. Upon excitation at 400 nm, transient absorption spectroscopy unveils photoinduced electron transfer from the host'...

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Detalles Bibliográficos
Autores principales: Ganta, Sudhakar, Borter, Jan-Hendrik, Drechsler, Christoph, Holstein, Julian J., Schwarzer, Dirk, Clever, Guido H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9552185/
https://www.ncbi.nlm.nih.gov/pubmed/36324316
http://dx.doi.org/10.1039/d2qo01339h