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Mechanical Activation of Forbidden Photoreactivity in Oxa-di-π-methane Rearrangement

[Image: see text] In this work, we demonstrate that the forbidden oxirane-type photoproduct (the cyclopropyl ketone photoproduct is the allowed one) of the oxa-di-π-methane photorearrangement can be obtained by mechanochemical control of the photoreactions. This control is achieved by the applicatio...

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Detalles Bibliográficos
Autores principales: Jodra, Alejandro, García-Iriepa, Cristina, Frutos, Luis Manuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9552220/
https://www.ncbi.nlm.nih.gov/pubmed/36166757
http://dx.doi.org/10.1021/acs.joc.2c00720