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Mechanical Activation of Forbidden Photoreactivity in Oxa-di-π-methane Rearrangement
[Image: see text] In this work, we demonstrate that the forbidden oxirane-type photoproduct (the cyclopropyl ketone photoproduct is the allowed one) of the oxa-di-π-methane photorearrangement can be obtained by mechanochemical control of the photoreactions. This control is achieved by the applicatio...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9552220/ https://www.ncbi.nlm.nih.gov/pubmed/36166757 http://dx.doi.org/10.1021/acs.joc.2c00720 |