Arylboronic Acid-Catalyzed Racemization of Secondary and Tertiary Alcohols

[Image: see text] The use of 2-carboxyphenylboronic acid (5 mol %) and oxalic acid (10 mol %) with 2-butanone as a solvent for the racemization of a range of enantiomerically pure secondary and tertiary alcohols is demonstrated. The process is postulated to proceed via reversible Brønsted acid-catal...

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Detalles Bibliográficos
Autores principales: Boyce, Gregory R., Musolino, Stefania F., Yang, Jianing, Smith, Andrew D., Taylor, James E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9552221/
https://www.ncbi.nlm.nih.gov/pubmed/36075004
http://dx.doi.org/10.1021/acs.joc.2c01602

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9552221/
https://www.ncbi.nlm.nih.gov/pubmed/36075004
http://dx.doi.org/10.1021/acs.joc.2c01602

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