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Structure and Reactivity of [Ru–Al] and [Ru–Sn] Heterobimetallic PPh(3)-Based Complexes

[Image: see text] Treatment of [Ru(PPh(3))(C(6)H(4)PPh(2))(2)H][Li(THF)(2)] with AlMe(2)Cl and SnMe(3)Cl leads to elimination of LiCl and CH(4) and formation of the heterobimetallic complexes [Ru(C(6)H(4)PPh(2))(2){PPh(2)C(6)H(4)AlMe(THF)}H] 5 and [Ru(PPh(3))(C(6)H(4)PPh(2))(PPh(2)C(6)H(4)SnMe(2))]...

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Detalles Bibliográficos
Autores principales: Isaac, Connie J., Miloserdov, Fedor M., Pécharman, Anne-Frédérique, Lowe, John P., McMullin, Claire L., Whittlesey, Michael K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9554919/
https://www.ncbi.nlm.nih.gov/pubmed/36249448
http://dx.doi.org/10.1021/acs.organomet.2c00344