BCC-Cu nanoparticles: from a transient to a stable allotrope by tuning size and reaction conditions

Metallic copper generally adopts an FCC structure. In this work, we detect highly unusual BCC-structured Cu nanoparticles as a transient intermediate during the H(2) reduction of a Cu(I) precursor, [Cu(4)O(t)Bu(4)], grafted onto the surface of partially dehydroxylated silica. The Cu BCC structure, a...

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Detalles Bibliográficos
Autores principales: Alfke, Jan L., Müller, Andreas, Clark, Adam H., Cervellino, Antonio, Plodinec, Milivoj, Comas-Vives, Aleix, Copéret, Christophe, Safonova, Olga V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9554935/
https://www.ncbi.nlm.nih.gov/pubmed/36189722
http://dx.doi.org/10.1039/d2cp03593f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9554935/
https://www.ncbi.nlm.nih.gov/pubmed/36189722
http://dx.doi.org/10.1039/d2cp03593f

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