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BCC-Cu nanoparticles: from a transient to a stable allotrope by tuning size and reaction conditions
Metallic copper generally adopts an FCC structure. In this work, we detect highly unusual BCC-structured Cu nanoparticles as a transient intermediate during the H(2) reduction of a Cu(I) precursor, [Cu(4)O(t)Bu(4)], grafted onto the surface of partially dehydroxylated silica. The Cu BCC structure, a...
Autores principales: | Alfke, Jan L., Müller, Andreas, Clark, Adam H., Cervellino, Antonio, Plodinec, Milivoj, Comas-Vives, Aleix, Copéret, Christophe, Safonova, Olga V. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9554935/ https://www.ncbi.nlm.nih.gov/pubmed/36189722 http://dx.doi.org/10.1039/d2cp03593f |
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