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BCC-Cu nanoparticles: from a transient to a stable allotrope by tuning size and reaction conditions
Metallic copper generally adopts an FCC structure. In this work, we detect highly unusual BCC-structured Cu nanoparticles as a transient intermediate during the H(2) reduction of a Cu(I) precursor, [Cu(4)O(t)Bu(4)], grafted onto the surface of partially dehydroxylated silica. The Cu BCC structure, a...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9554935/ https://www.ncbi.nlm.nih.gov/pubmed/36189722 http://dx.doi.org/10.1039/d2cp03593f |