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Synergistic effects of CH(3)CO(2)H and Ca(2+) on C–H bond activation by MnO(4)(−)
The activation of metal-oxo species with Lewis acids is of current interest. In this work, the effects of a weak Brønsted acid such as CH(3)CO(2)H and a weak Lewis acid such as Ca(2+) on C–H bond activation by KMnO(4) have been investigated. Although MnO(4)(−) is rather non-basic (pK(a) of MnO(3)(OH...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9555569/ https://www.ncbi.nlm.nih.gov/pubmed/36320399 http://dx.doi.org/10.1039/d2sc03089f |