Palladium-catalyzed intramolecular Heck dearomative gem-difluorovinylation of indoles

A palladium-catalyzed dearomative reaction of indoles has been developed through a domino Heck/gem-difluorovinylation sequence. By taking advantage of a difluorocarbene precursor (ClCF(2)COONa), the palladium difluorocarbene ([Pd][double bond, length as m-dash]CF(2)) species was formed smoothly. The...

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Detalles Bibliográficos
Autores principales: Wang, Gang, Li, Wenqi, Liu, Tianxiang, Zhang, Yonghong, Wang, Bin, Xue, Fei, Jin, Weiwei, Ma, Caiyan, Xia, Yu, Liu, Chenjiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9555723/
https://www.ncbi.nlm.nih.gov/pubmed/36320398
http://dx.doi.org/10.1039/d2sc03169h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9555723/
https://www.ncbi.nlm.nih.gov/pubmed/36320398
http://dx.doi.org/10.1039/d2sc03169h

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