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Characteristic (1)H NMR spectra of β-d-ribofuranosides and ribonucleosides: factors driving furanose ring conformations

A series of β-d-ribofuranosides and ribonucleosides fused with 2,3-O-isopropylidene ring was synthesized and studied in terms of their conformational preferences. Based on the (1)H NMR spectra, DFT calculations, and X-ray analysis the E(0)-like and E(4)-like conformations adopted by these furanoside...

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Detalles Bibliográficos
Autores principales: Walczak, Dominik, Sikorski, Artur, Grzywacz, Daria, Nowacki, Andrzej, Liberek, Beata
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9557318/
https://www.ncbi.nlm.nih.gov/pubmed/36320749
http://dx.doi.org/10.1039/d2ra04274f