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The Contribution of Proton-Donor pKa on Reactivity Profiles of [FeFe]-hydrogenases

The [FeFe]-hydrogenases are enzymes that catalyze the reversible activation of H(2) coupled to the reduction–oxidation of electron carriers. Members of the different taxonomic groups of [FeFe]-hydrogenases display a wide range of preference, or bias, for H(2) oxidation or H(2) production reactions,...

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Detalles Bibliográficos
Autores principales: Kisgeropoulos, Effie C., Bharadwaj, Vivek S., Mulder, David W., King, Paul W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9563086/
https://www.ncbi.nlm.nih.gov/pubmed/36246213
http://dx.doi.org/10.3389/fmicb.2022.903951