The Conversion of Superoxide to Hydroperoxide on Cobalt(III) Depends on the Structural and Electronic Properties of Azole-Based Chelating Ligands

Conversion from superoxide (O(2)(−)) to hydroperoxide (OOH(−)) on the metal center of oxygenases and oxidases is recognized to be a key step to generating an active species for substrate oxidation. In this study, reactivity of cobalt(III)-superoxido complexes supported by facially-capping tridentate...

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Detalles Bibliográficos
Autores principales: Nishiura, Toshiki, Ohta, Takehiro, Ogura, Takashi, Nakazawa, Jun, Okamura, Masaya, Hikichi, Shiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571172/
https://www.ncbi.nlm.nih.gov/pubmed/36234952
http://dx.doi.org/10.3390/molecules27196416

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571172/
https://www.ncbi.nlm.nih.gov/pubmed/36234952
http://dx.doi.org/10.3390/molecules27196416

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