Self-Assembly of Supramolecular Architectures Driven by σ-Hole Interactions: A Halogen-Bonded 2D Network Based on a Diiminedibromido Gold(III) Complex and Tribromide Building Blocks

The reaction of the complex [Au(phen)Br(2)](PF(6)) (phen = 1,10-phenanthroline) with molecular dibromine afforded {[Au(phen)Br(2)](Br(3))}(∞) (1). Single crystal diffraction analysis showed that the [Au(phen)Br(2)](+) complex cations were bridged by asymmetric tribromide anions to form infinite zig-...

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Detalles Bibliográficos
Autores principales: Aragoni, M. Carla, Cherchi, M. Francesca, Lippolis, Vito, Pintus, Anna, Podda, Enrico, Slawin, Alexandra M. Z., Woollins, J. Derek, Arca, Massimiliano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571214/
https://www.ncbi.nlm.nih.gov/pubmed/36234826
http://dx.doi.org/10.3390/molecules27196289

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571214/
https://www.ncbi.nlm.nih.gov/pubmed/36234826
http://dx.doi.org/10.3390/molecules27196289

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