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Self-Assembly of Supramolecular Architectures Driven by σ-Hole Interactions: A Halogen-Bonded 2D Network Based on a Diiminedibromido Gold(III) Complex and Tribromide Building Blocks
The reaction of the complex [Au(phen)Br(2)](PF(6)) (phen = 1,10-phenanthroline) with molecular dibromine afforded {[Au(phen)Br(2)](Br(3))}(∞) (1). Single crystal diffraction analysis showed that the [Au(phen)Br(2)](+) complex cations were bridged by asymmetric tribromide anions to form infinite zig-...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571214/ https://www.ncbi.nlm.nih.gov/pubmed/36234826 http://dx.doi.org/10.3390/molecules27196289 |