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A Novel Family of Cage-like (CuLi, CuNa, CuK)-phenylsilsesquioxane Complexes with 8-Hydroxyquinoline Ligands: Synthesis, Structure, and Catalytic Activity

The first examples of metallasilsesquioxane complexes, including ligands of the 8-hydroxyquinoline family 1–9, were synthesized, and their structures were established by single crystal X-ray diffraction using synchrotron radiation. Compounds 1–9 tend to form a type of sandwich-like cage of Cu(4)M(2)...

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Detalles Bibliográficos
Autores principales: Bilyachenko, Alexey N., Khrustalev, Victor N., Zueva, Anna Y., Titova, Ekaterina M., Astakhov, Grigorii S., Zubavichus, Yan V., Dorovatovskii, Pavel V., Korlyukov, Alexander A., Shul’pina, Lidia S., Shubina, Elena S., Kozlov, Yuriy N., Ikonnikov, Nikolay S., Gelman, Dmitri, Shul’pin, Georgiy B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571593/
https://www.ncbi.nlm.nih.gov/pubmed/36234735
http://dx.doi.org/10.3390/molecules27196205