5,5,5-Trichloropent-3-en-one as a Precursor of 1,3-Bi-centered Electrophile in Reactions with Arenes in Brønsted Superacid CF(3)SO(3)H. Synthesis of 3-Methyl-1-trichloromethylindenes

Reactions of 5,5,5-trichloropent-3-en-2-one Cl(3)CCH=CHC(=O)Me with arenes in Brønsted superacid CF(3)SO(3)H at room temperature for 2 h–5 days afford 3-methyl-1-trichloromethylindenes, a novel class of indene derivatives. The key reactive intermediate, O-protonated form of starting compound Cl(3)CC...

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Detalles Bibliográficos
Autores principales: Shershnev, Ivan A., Boyarskaya, Irina A., Vasilyev, Aleksander V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9573653/
https://www.ncbi.nlm.nih.gov/pubmed/36235211
http://dx.doi.org/10.3390/molecules27196675

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9573653/
https://www.ncbi.nlm.nih.gov/pubmed/36235211
http://dx.doi.org/10.3390/molecules27196675

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