Three-center-four-electron halogen bond enables non-metallic complex catalysis for Mukaiyama-Mannich-type reaction

The three-center-four-electron halogen bond (3c4e X-bond) presents a fundamental design concept for catalysis. By integrating halogen(I) (X(+): I(+) or Br(+)), the bis-pyridyl ligand NN, and a non-nucleophilic counteranion Y, we developed non-metallic complex catalysts, [N···X···N]Ys, that exhibited...

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Detalles Bibliográficos
Autores principales: Oishi, Shunya, Fujinami, Takeshi, Masui, Yu, Suzuki, Toshiyasu, Kato, Masayuki, Ohtsuka, Naoya, Momiyama, Norie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9579028/
https://www.ncbi.nlm.nih.gov/pubmed/36274952
http://dx.doi.org/10.1016/j.isci.2022.105220

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9579028/
https://www.ncbi.nlm.nih.gov/pubmed/36274952
http://dx.doi.org/10.1016/j.isci.2022.105220

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