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Three-center-four-electron halogen bond enables non-metallic complex catalysis for Mukaiyama-Mannich-type reaction
The three-center-four-electron halogen bond (3c4e X-bond) presents a fundamental design concept for catalysis. By integrating halogen(I) (X(+): I(+) or Br(+)), the bis-pyridyl ligand NN, and a non-nucleophilic counteranion Y, we developed non-metallic complex catalysts, [N···X···N]Ys, that exhibited...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Elsevier
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9579028/ https://www.ncbi.nlm.nih.gov/pubmed/36274952 http://dx.doi.org/10.1016/j.isci.2022.105220 |