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C–H Activation by Isolable Cationic Bis(phosphine) Cobalt(III) Metallacycles

[Image: see text] Five- and six-coordinate cationic bis(phosphine) cobalt(III) metallacycle complexes were synthesized with the general structures, [(depe)Co(cycloneophyl)(L)(L′)][BAr(F)(4)] (depe = 1,2-bis(diethylphosphino)ethane; cycloneophyl = [κ-C:C-(CH(2)C(Me)(2))C(6)H(4)]; L/L′ = pyridine, piv...

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Detalles Bibliográficos
Autores principales: Whitehurst, William G., Kim, Junho, Koenig, Stefan G., Chirik, Paul J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9585578/
https://www.ncbi.nlm.nih.gov/pubmed/36194198
http://dx.doi.org/10.1021/jacs.2c08865