Cargando…

Nickel-Catalyzed Enantioselective Coupling of Aldehydes and Electron-Deficient 1,3-Dienes Following an Inverse Regiochemical Course

[Image: see text] The nickel catalyzed reductive coupling of aldehydes with sorbate esters and related electron-deficient 1,3-dienes are known in the literature to occur at the π-bond proximal to the ester to afford aldol-type products. In stark contrast to this established path, a VAPOL-derived pho...

Descripción completa

Detalles Bibliográficos
Autores principales: Davies, Thomas Q., Kim, Jae Yeon, Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9585590/
https://www.ncbi.nlm.nih.gov/pubmed/36194199
http://dx.doi.org/10.1021/jacs.2c09328