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Ionic supramolecular polymerization of water-soluble porphyrins: balancing ionic attraction and steric repulsion to govern stacking

We have synthesized novel water-soluble anionic porphyrin monomers that undergo pH-regulated ionic supramolecular polymerization in aqueous media. By tuning the total charge of the monomer, we selectively produced two different supramolecular polymers: J- and H-stacked. The main driving force toward...

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Detalles Bibliográficos
Autores principales: Kanzaki, Chisako, Yoneda, Hiroshi, Nomura, Shota, Maeda, Takato, Numata, Munenori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9597584/
https://www.ncbi.nlm.nih.gov/pubmed/36337941
http://dx.doi.org/10.1039/d2ra05542b