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Interplay between β-Diimino and β-Diketiminato Ligands in Nickel Complexes Active in the Proton Reduction Reaction

[Image: see text] Two Ni complexes are reported with κ(4)-P(2)N(2) β-diimino (BDI) ligands with the general formula [Ni(XBDI)](BF(4))(2), where BDI is N-(2-(diphenylphosphaneyl)ethyl)-4-((2-(diphenylphosphaneyl)ethyl)imino)pent-2-en-2-amine and X indicates the substituent in the α-carbon intradiimin...

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Detalles Bibliográficos
Autores principales: Jameei Moghaddam, Navid, Gil-Sepulcre, Marcos, Wang, Jia-Wei, Benet-Buchholz, Jordi, Gimbert-Suriñach, Carolina, Llobet, Antoni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9597662/
https://www.ncbi.nlm.nih.gov/pubmed/36196853
http://dx.doi.org/10.1021/acs.inorgchem.2c02150